An oriented ID coordination/organometallic dimetallic molecular wire with Ag-Pd metal-metal bonds

被引：54

作者：

Braunstein, P

Frison, U

Oberbeckmann-Winter, N

Morise, X

Messaoudi, A

Bénard, M

Rohmer, MM

Welter, R

机构：

[1] Univ Strasbourg 1, Lab Chim Quant, UMR 7551, CNRS,Inst Le Bel, F-67070 Strasbourg, France

[2] Univ Strasbourg 1, Lab DECMET, UMR 7513, CNRS,Inst Le Bel, F-67070 Strasbourg, France

[3] Univ Strasbourg 1, Chim Coordinat Lab, UMR 7513, CNRS,Inst Le Bel, F-67070 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期

关键词：

coordination polymers; density functional calculations; heterometallic complexes; ligand reactivity; metal-metal interactions;

D O I：

10.1002/anie.200461291

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A subtle electronic balance between covalent and dative interactions involving coordinated phosphanyl iminolate ligands results in the formation of an oriented, 1 D coordination/organometallic heterodimetallic polymer with Pd-Ag interactions (shown as purple and green, respectively). In the solid-state, the lipophilic aromatic rings of the infinite zigzag chains are all on one side of the planes of metal ions, which results in an unusual layered structure.

引用

收藏

页码：6120 / 6125

页数：6

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