A torsion study on the sublimation process of InCl3

被引:20
作者
Brunetti, B [1 ]
Piacente, V [1 ]
Scardala, P [1 ]
机构
[1] Univ Rome La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
关键词
D O I
10.1021/je970188a
中图分类号
O414.1 [热力学];
学科分类号
摘要
The temperature dependence of the total vapor pressure above InCl3, as measured by the torsion-effusion method, is expressed by the equation log(p/kPa) = 12.76 +/- 0.15 - (8570 +/- 200)/(T/K) in the temperature range 495 to 648 K. In addition to InCl3(g), the presence of the dimeric form In2Cl6(g) was observed in the vapor at high temperature. The sublimation process InCl3(s) = InCl3(g) was studied, and the standard enthalpy of this reaction was found to be (158 +/- 4) kJ mol(-1).
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页码:101 / 104
页数:4
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