The use of Nafion-H®/NaNO2 as an efficient procedure for the chemoselective N-nitrosation of secondary amines under mild and heterogeneous conditions

被引:66
作者
Zolfigol, MA [1 ]
Habibi, D
Mirjalili, BF
Bamoniri, A
机构
[1] Bu Ali Sina Univ, Coll Sci, Dept Chem, Hamadan 65174, Iran
[2] Yazd Univ, Coll Sci, Dept Chem, Yazd, Iran
关键词
Nafion-H (R); chemoselective N-nitrosation; secondary amines; N-nitrosoamines;
D O I
10.1016/S0040-4039(03)00578-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A combination of Nafion-H(R) and sodium nitrite in the presence of wet SiO2 was used as an effective agent for the N-nitrosation of secondary amines under mild and heterogeneous conditions in good to excellent yields. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3345 / 3349
页数:5
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