INVITED TOPICAL REVIEW The structure of ambient water

被引:201
作者
Clark, Gary N. I. [1 ]
Cappa, Christopher D. [2 ]
Smith, Jared D. [3 ]
Saykally, Richard J. [3 ,5 ]
Head-Gordon, Teresa [1 ,4 ]
机构
[1] Univ Calif Berkeley, Dept Bioengn, Berkeley, CA 94720 USA
[2] Univ Calif Davis, Dept Civil & Environm Engn, Davis, CA 95616 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
[4] Univ Calif Berkeley, Lawrence Berkeley Lab, Phys Biosci Div, Berkeley, CA 94720 USA
[5] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
关键词
x-ray and neutron scattering; x-ray absorption and emission spectroscopy; mixture and continuum models; empirical and ab initio theory; X-RAY-SCATTERING; HYDROGEN-BOND NETWORK; ENHANCED DENSITY-FLUCTUATIONS; RADIAL-DISTRIBUTION FUNCTIONS; LIQUID WATER; EMISSION SPECTROSCOPY; MOLECULAR-DYNAMICS; ISOTHERMAL COMPRESSIBILITY; ABSORPTION SPECTROSCOPY; SUPERCOOLED WATER;
D O I
10.1080/00268971003762134
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We review the spectroscopic techniques and scattering experiments used to probe the structure of water, and their interpretation using empirical and ab initio models, over the last 5 years. We show that all available scientific evidence overwhelmingly favors the view of classifying water near ambient conditions as a uniform, continuous tetrahedral liquid. While there are controversial issues in our understanding of water in the supercooled state, in confinement, at interfaces, or in solution, there is no real controversy in what is understood as regards bulk liquid water under ambient conditions.
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页码:1415 / 1433
页数:19
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