High magnetic field spin resonance in nearly stoichiometric LiNiO2:: evidences for magnetic cluster formation

被引：18

作者：

Barra, AL

Chouteau, G

Stepanov, A

Delmas, C

机构：

[1] CNRS, MPI, High Magnet Field Lab, F-38042 Grenoble 9, France

[2] Univ Bordeaux 1, Lab Chim Solides, F-33405 Talence, France

来源：

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS | 1998年 / 177卷 / 177-181期

关键词：

clusters; ferromagnetic resonance; magnetic oxides; Jahn-Teller effect;

D O I：

10.1016/S0304-8853(97)00729-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Using high magnetic field ESR spectroscopy we have performed resonance measurements of LiNiO2 up to 245 GHz between 4 and 300 K. For the first time we have detected separately the ESR spectra due to the Ni3+ ions in LiNiO2 matrix and the extra-nickel magnetic clusters. This allows us to make a detailed analysis of the magnetic properties of LiNiO2. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：783 / 784

页数：2

共 3 条

[1] Optimization of the composition of the Li1-zNi1+zO2 electrode materials: Structural, magnetic, and electrochemical studies [J].