Polynitrogen strong bases: 1-New syntheses of biguanides and their catalytic properties in transesterification reactions

被引:59
作者
Gelbard, G [1 ]
Vielfaure-Joly, F [1 ]
机构
[1] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France
关键词
D O I
10.1016/S0040-4039(98)00300-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new and convenient method has been developed for the synthesis of soluble and polystyrene-supported biguanides by the nucleophilic addition of guanidines such as TMG and TDB to diisopropyl-, dicyclohexyl- and polymericarbodi-imide. These biguanides are excellent catalysts for the transesterification. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2743 / 2746
页数:4
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