Synthesis and structure of a twisted, colossal quinone

被引：16

作者：

Watson, JA

Pascal, RA

Ho, DM

Kilway, KV ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA

[2] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 26期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)00773-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A very large quinone was prepared by the double Diels-Alder reaction of 2,5,9,12-tetra(t-butyl)diacenaphtho[1,2-b: 1',2'-d]thiophene and benzoquinone. The crystal structure of the polycyclic product shows that the central anthraquinone ring system is quite twisted (50 degrees), and the overall structure possesses approximate D-2 symmetry. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

收藏

页码：5005 / 5008

页数：4

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