Complexation of triptycene-based cylindrical macrotricyclic polyether toward diquaternary salts: Ion-controlled binding and release of the guests

被引:54
作者
Han, Tao
Zong, Qian-Shou
Chen, Chuan-Feng [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Biol Chem Lab, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
关键词
D O I
10.1021/jo070035i
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Triptycene-based cylindrical macrotricyclic polyether 1 has been proved to be an efficient host for the complexation with diquaternary salts in solution and in the solid state. Moreover, it was also found that binding and release of the guest molecules could be easily controlled by the addition and removal of potassium ions.
引用
收藏
页码:3108 / 3111
页数:4
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