(THF)3LiCl as a ligand for low-coordinate Fe(II):: Crystal structure of [(Me3Si)2N]2Fe(μ-Cl)Li(THF)3

被引：20

作者：

Siemeling, U ^{[1
]}

Vorfeld, U ^{[1
]}

Neumann, B ^{[1
]}

Stammler, HG ^{[1
]}

机构：

[1] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 22期

关键词：

D O I：

10.1021/ic000086x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pale-green, air-sensitive complex [(Me2Si)2N]2Fe(μ-Cl)Li(THF)3 was synthesized serendipitously by the reaction of iron(II) chloride in THF with 1 equiv of KN(SiMe3)2 and subsequent addition of CpLi and was structurally characterized by X-ray diffraction. ClLi-(THF)3 acts as a ligand and appears to be a better donor than THF for the three-coordinate trigonal-planar Fe atom.

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页码：5159 / 5160

页数：2

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