Concomitant coordination of vinylidene and carbene ligands made possible at ruthenium(II)

被引：16

作者：

Bianchini, C ^{[1
]}

Purches, G ^{[1
]}

Zanobini, F ^{[1
]}

Peruzzini, M ^{[1
]}

机构：

[1] CNR, Ist Studio Stereochim & Energet Composti Coor, I-50132 Florence, Italy

来源：

INORGANICA CHIMICA ACTA | 1998年 / 272卷 / 1-2期

关键词：

vinylidene complexes; carbene complexes; aminodiphosphine ligands; ruthenium complexes;

D O I：

10.1016/S0020-1693(97)05877-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Removal of one chloride ligand from the aminocarbene fac-[(PNP)RuCl2(C{N(H)Ph}{CH2Ph})] in THF followed by treatment with phenylacetylene yields the ruthenium(II) complex mer-[(PNP)RuCl{C=C(H)Ph}(C{N(H)Ph}{CH2Ph})]PF6 (4). Complex 4 represents the first example of a transition metal complex with the simultaneous coordination of vinylidene and carbene ligands. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：1 / 3

页数：3

共 37 条

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