Anion recognition through hydrogen bonding: a simple, yet highly sensitive, luminescent metal-complex receptor

被引：238

作者：

Sun, SS ^{[1
]}

Lees, AJ ^{[1
]}

机构：

[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b004541l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new luminescent rhenium(i) polypyridyl-based receptor for a variety of inorganic anions has been designed and synthesized and this artificial receptor shows high affinities for halides, cyanide and acetate anions with binding constants as high as 10(4)-10(5) M-1 and a detection limit as low as 10(-8) M in CH2Cl2 solution.

引用

页码：1687 / 1688

页数：2

共 20 条

[1]

Beer PD, 1997, PROG INORG CHEM, V46, P1, DOI 10.1002/9780470166475.ch1

[2]

BELL DA, 1996, COMPREHENSIVE SUPRAM, V2, pCH14

[3] Recognition of anions through NH-pi hydrogen bonds in a bicyclic cyclophane-selectivity for nitrate [J].