Dinitrogen tetroxide copper nitrate complex [Cu(NO3)2.N2O4] as a new nitrosating agent for catalytic coupling of thiols via thionitrite

被引：87

作者：

Iranpoor, N ^{[1
]}

Firouzabadi, H ^{[1
]}

Zolfigol, MA ^{[1
]}

机构：

[1] Shiraz Univ, Dept Chem, Shiraz 71454, Iran

来源：

SYNTHETIC COMMUNICATIONS | 1998年 / 28卷 / 02期

关键词：

D O I：

10.1080/00397919808005729

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic and efficient oxidative coupling of thiols to disulfides is described using Cu(NO3)(2) . N2O4 as a new and efficient nitrosating agent in acetone at room temperature. The reaction is shown to occur immediately through the intermediacy of a thionitrite.

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页码：367 / 375

页数：9

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