A homodecoupled diffusion experiment for the analysis of complex mixtures by NMR

被引：24

作者：

Cobas, JC ^{[1
]}

Martín-Pastor, M ^{[1
]}

机构：

[1] Univ Santiago, RIAIDT, Lab Integral Dinam & Estructura Biomol Jose R, Unidade Resonancia Magnet, Santiago De Compostela 15782, Spain

来源：

JOURNAL OF MAGNETIC RESONANCE | 2004年 / 171卷 / 01期

关键词：

NMR; diffusion; DOSY; J-resolved; mixture analysis;

D O I：

10.1016/j.jmr.2004.07.016

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Diffusion ordered spectroscopy (DOSY) relies on differences in translation diffusion as a means to separate components in a solution mixture. However, the analysis of spectra of mixtures can be problematic because spectral overlap. It is the aim of this article to propose a pulse sequence and processing method that leads to a complete 2D homodecoupled-DOSY experiment. This experiment offers several advantages that could extend the range of applications to more complex mixtures by achieving important improvements in both signal dispersion and sensitivity. (C) 2004 Elsevier Inc. All rights reserved.

引用

页码：20 / 24

页数：5

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