Preparation of phenolic chiral crown ethers and podands and their enantiomer recognition ability toward secondary amines

被引：31

作者：

Hirose, K ^{[1
]}

Fujiwara, A

Matsunaga, K

Aoki, N

Tobe, Y

机构：

[1] Osaka Univ, Fac Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan

[2] Japan Sci & Technol Corp, JST, CREST, Toyonaka, Osaka 5608531, Japan

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 05期

关键词：

ENANTIOSELECTIVE COMPLEXATION; DERIVATIVES; 2,4-DIMETHYL-3-OXAPENTANE-1,5-DIOL; RECEPTORS; BEHAVIOR; BINDING; SUBUNIT; DRUGS;

D O I：

10.1016/S0957-4166(03)00031-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Phenolic pseudo-24-crown-8 (S,S)-3, pseudo-27-crown-9 (S,S)-4, and podands (R,R)-5 and (R,R)-6 possessing phenyl groups as chiral barriers were prepared and their chiral recognition properties toward secondary neutral amines were examined. Pseudo-24-crown-8 (S,S)-3 and podand (R,R)-5 showed sufficient binding ability and moderate chiral recognition ability toward secondary amines. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：555 / 566

页数：12

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