A new proton-conductive copper coordination polymer, (HOC3H6)2dtoaCu (dtoa = dithiooxamide)

被引：28

作者：

Nagao, Y ^{[1
]}

Ikeda, R

Iijima, K

Kubo, T

Nakasuji, K

Kitagawa, H

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan

[3] JST, PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

SYNTHETIC METALS | 2003年 / 135卷 / 1-3期

关键词：

proton conduction; coordination polymer; a. c. conductivity measurements; transport measurements; proton exchange membrane;

D O I：

10.1016/S0379-6779(02)00914-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new copper coordination polymer, (HOC3H6)(2)dtoaCu (dtoa = dithiooxamide), was synthesized. The crystal structure is considered to be similar to that of a two-dimensional (2-D) coordination polymer (HOC2H4)(2)dtoaCu. The concentration of water molecules included in this polymer was found by thermogravimetric (TG) analysis to increase with relative humidity (RH) upon the sample preservation. The a.c. conductivity measurements with an impedance analyzer were carried out for (HOC3H6)(2)dtoaCu in order to estimate the proton conductivity (sigmap). The log sigmap was linearly increased from 3.3 x 10(-9) to 2.0 x 10(-6) S cm(-1) with RH from 58 to 100% at 300 K. These facts imply that the proton conduction depends on the quantity of water molecules contained in the polymer.

引用

页码：283 / 284

页数：2

共 7 条

[1]

Colomban P., 1992, Proton conductors: solids, membranes, and gels: materials and devices

[2] Hydrogen-induced properties of copper coordination polymer:: catena-μ-N,N′-bis-(hydroxyethyl) dithiooxamidatocopper(II) [J].