Pore size engineering on MCM-41:: Selectivity tuning of heterogenized AlCl3 for the synthesis of linear alkyl benzenes

被引：49

作者：

Hu, XC ^{[1
]}

Foo, ML ^{[1
]}

Chuah, GK ^{[1
]}

Jaenicke, S ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore

来源：

JOURNAL OF CATALYSIS | 2000年 / 195卷 / 02期

关键词：

D O I：

10.1006/jcat.2000.2965

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

AlCl3 has been successfully immobilized on MCM-41 mesoporous silica of different pore sizes to form a novel shape-selective catalyst for the Friedel-Crafts alkylation of benzene with long-chain olefins (linear 1-olefins with a chain length of 6 to 16 carbon atoms). The selectivity toward the monoalkylated product is strongly influenced by the pore size of the carrier material. This demonstrates the opportunities offered by the micelle-templating method to tailor shape-selective catalysts for reactions with bigger molecules. (C) 2000 Academic Press.

引用

页码：412 / 415

页数：4

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