Electron effective mass and phonon modes in GaAs incorporating boron and indium

被引:26
作者
Hofmann, T. [1 ]
Schubert, M.
Leibiger, G.
Gottschalch, V.
机构
[1] Univ Nebraska, Dept Elect Engn, Lincoln, NE 68588 USA
[2] Univ Nebraska, Nebraska Ctr Mat & Nanosci, Lincoln, NE 68588 USA
[3] Freiberger Compound Mat GmbH, D-09599 Freiberg, Germany
[4] Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, D-04103 Leipzig, Germany
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2735669
中图分类号
O59 [应用物理学];
学科分类号
摘要
The strain-free boron- and indium-containing GaAs compounds are promising candidates for III-V semiconductor solar cell absorber materials with lattice match to GaAs, for which experimental data of the electronic band structure are widely unknown. For nondegenerate, silicon-doped, n-type B0.03In0.06Ga0.91As with band-gap energy of 1.36 eV, determined by near-infrared ellipsometry, a strong increase of the electron effective mass of 44% in B0.03In0.06Ga0.91As compared to In0.06Ga0.94As is obtained from far-infrared magneto-optic generalized ellipsometry studies. The authors thereby obtain the vibrational lattice mode behavior. For BAs, an experimentally obscure compound, the curvature of the Gamma-point conduction band thus extrapolates to the free electron mass. (C) 2007 American Institute of Physics.
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页数:3
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