Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block

被引：103

作者：

He, Z

He, C

Gao, EQ

Wang, ZM

Yang, XF

Liao, CS

Yan, CH ^{[1
]}

机构：

[1] Beijing Univ, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

[2] Beijing Univ, PKU HKU, Coll Chem & Mol Engn, Joint Lab Rare Earth Mat & Bioorgan Chem, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 07期

关键词：

D O I：

10.1021/ic026271n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One-dimensional lanthanice-transition heterometallic chains of squares, {LnNi(2)L(3)(HL)(DMF)(4)(CIO4)(4).S}(infinity) (Ln = Gd and Tb; HL is the Schiff base obtained by the condensation of 2-pyridylaldehyde with isonicotinic hydrazide N-oxide; S = solvent) and {LnNi(2)L(4)-(DMF)(4)(CIO4)(3).S}(infinity) (Ln = Dy; S = solvent), were synthesized by self-assembly between well-designed orthogonal metalloligands [Ni-(HL)L](+) and the Ln(III) ions, which act as the bridging units and nodes, respectively.

引用

页码：2206 / 2208

页数：3

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