Kinetics of a reactive dye adsorption onto dolomitic sorbents

被引:335
作者
Walker, GM [1 ]
Hansen, L [1 ]
Hanna, JA [1 ]
Allen, SJ [1 ]
机构
[1] Queens Univ Belfast, Sch Chem Engn, Belfast BT9 5AG, Antrim, North Ireland
关键词
adsorption; dyestuff; wastewater; dolomite; kinetics;
D O I
10.1016/S0043-1354(02)00540-7
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
A novel wastewater treatment technique has been investigated, for reactive dye removal, in batch kinetic systems. These experimental studies have indicated that charred dolomite has the potential to act as an adsorbent for the removal of Brilliant Red reactive dye from aqueous solution. The effect of initial dye concentration, adsorbent mass:liquid volume ratio, and agitation speed on dye removal have been determined with the experimental data mathematically described using empirical external mass transfer and intra-particle diffusion models. The experimental data show conformity with an adsorption process, with the removal rate heavily dependent on both external mass transfer and intra-particle diffusion. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2081 / 2089
页数:9
相关论文
共 14 条
[1]  
ALLEN S, 1992, J CHEM TECHNOL BIOT, V54, P271
[2]   INTRAPARTICLE DIFFUSION OF A BASIC DYE DURING ADSORPTION ONTO SPHAGNUM PEAT [J].
ALLEN, SJ ;
MCKAY, G ;
KHADER, KYH .
ENVIRONMENTAL POLLUTION, 1989, 56 (01) :39-50
[3]  
BOYNTON RS, 1967, CHEM TECHNOLOGY LIME
[4]  
CHURCHLEY JH, 1993, TEXTILE EFFLUENT COL
[5]   FLUID-PARTICLE AND INTRAPARTICLE MASS-TRANSPORT RATES IN SLURRIES [J].
FURUSAWA, T ;
SMITH, JM .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1973, 12 (12) :197-203
[6]  
FURUSAWA T, 1974, AICHE J, V20, P88, DOI 10.1002/aic.690200111
[7]   THE EXTERNAL MASS-TRANSFER OF BASIC AND ACIDIC DYES ON WOOD [J].
MCKAY, G ;
MCCONVEY, IF .
JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1981, 31 (07) :401-408
[8]   THE ADSORPTION OF DYES IN CHITIN .3. INTRAPARTICLE DIFFUSION-PROCESSES [J].
MCKAY, G ;
BLAIR, HS ;
GARDNER, J .
JOURNAL OF APPLIED POLYMER SCIENCE, 1983, 28 (05) :1767-1778
[9]   Investigations on the adsorption properties and porosity of natural and thermally treated dolomite samples [J].
Staszczuk, P ;
Stefaniak, E ;
Bilinski, B ;
Szymanski, E ;
Dobrowolski, R ;
Jayaweera, SAA .
POWDER TECHNOLOGY, 1997, 92 (03) :253-257
[10]   On the adsorption of chromium(VI) ions on dolomite and 'dolomitic sorbents' [J].
Stefaniak, E ;
Dobrowolski, R ;
Staszczuk, P .
ADSORPTION SCIENCE & TECHNOLOGY, 2000, 18 (02) :107-115