Transition metal-catalyzed synthesis of (E)-2-(Alkylthio)alka-1,3-dienes from allenes and dialkyl disulfides with concomitant hydride transfer

被引:30
作者
Arisawa, M [1 ]
Suwa, A [1 ]
Fujimoto, K [1 ]
Yamaguchi, M [1 ]
机构
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
关键词
(E)-2-(alkylthio)alka-1,3-diene; allene; diselenide; disulfide; hydride transfer; rhodium;
D O I
10.1002/adsc.200303010
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Reaction of dialkyl disulfides or diselenides with allenes is catalyzed by a rhodium-phosphine complex and trifluoromethanesulfonic acid giving (E)-2-alkylthio(seleno)-1,3-dienes and (E)-2-alkylthio(seleno)-2-alkenes. Unlike the reaction of alkynes, the reaction of allene is accompanied by hydride transfer.
引用
收藏
页码:560 / 563
页数:4
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