Reactive nanostructured carbon as an effective doping agent for MgB2

被引:23
作者
Gruner, W. [1 ]
Herrmann, M. [1 ]
Nilsson, A. [1 ]
Hermann, H. [1 ]
Hassler, W. [1 ]
Holzapfel, B. [1 ]
机构
[1] Leibniz Inst Solid State & Mat Res, D-01171 Dresden, Germany
关键词
D O I
10.1088/0953-2048/20/7/003
中图分类号
O59 [应用物理学];
学科分类号
摘要
AMgB(2-x)C(x) superconductor was prepared with reactive nanostructured carbon up to nominal x = 0.316 by high- energy ball milling. These products crystallize at temperatures below 700 degrees C, forming mainly MgB2-xCx with a particle size of about 20 nm and with lattice- dissolved carbon content up to about x = 0.13 under normal pressure conditions, and minor MgB4. The nominal higher addition of reactive nanostructured carbon does not have an influence on the a- axis of the MgB2-xCx structure. The superconducting behaviour reflects the optimum interplay of the lattice- dissolved carbon, which influences the carrier density, and the homogeneously distributed carbon, which probably acts as a pinning centre. For the sample with a nominal x = 0.221, the critical current density ( J(c)) increased by approximately one order of magnitude to J(c) = 1.7 x 10(4) A cm(-2) at 9 T and 4.2 K compared to the undoped MgB2.
引用
收藏
页码:601 / 606
页数:6
相关论文
共 39 条
[1]   Co-addition into WgB2:: The structural and electronic properties of (MgB2)2-xCox [J].
Aksan, M. A. ;
Yakinci, M. E. ;
Guldeste, A. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2006, 424 (1-2) :33-40
[2]   Peculiarities in the carbon substitution of MgB2 [J].
Balaselvi, SJ ;
Gayathri, N ;
Bharathi, A ;
Sastry, VS ;
Hariharan, Y .
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2004, 407 (1-2) :31-38
[3]   MAGNETIZATION OF HIGH-FIELD SUPERCONDUCTORS [J].
BEAN, CP .
REVIEWS OF MODERN PHYSICS, 1964, 36 (1P1) :31-+
[4]   Carbon solubility and superconductivity in MgB2 [J].
Bharathi, A ;
Balaselvi, SJ ;
Kalavathi, S ;
Reddy, GLN ;
Sastry, VS ;
Hariharan, Y ;
Radhakrishnan, TS .
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2002, 370 (04) :211-218
[5]   Vaporization thermodynamics of MgB2 and MgB4 [J].
Brutti, S ;
Ciccioli, A ;
Balducci, G ;
Gigli, G ;
Manfrinetti, P ;
Palenzona, A .
APPLIED PHYSICS LETTERS, 2002, 80 (16) :2892-2894
[6]   The substitutional chemistry of MgB2 [J].
Cava, RJ ;
Zandbergen, HW ;
Inumaru, K .
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS, 2003, 385 (1-2) :8-15
[7]   Ball milling induced low-temperature carbothermic reduction of ilmenite [J].
Chen, Y ;
Hwang, T ;
Williams, JS .
MATERIALS LETTERS, 1996, 28 (1-3) :55-58
[8]   Effect of carbon nanotube doping on critical current density of MgB2 superconductor [J].
Dou, SX ;
Yeoh, WK ;
Horvat, J ;
Ionescu, M .
APPLIED PHYSICS LETTERS, 2003, 83 (24) :4996-4998
[9]   Modification of carbon nanostructures by high energy ball-milling under argon and hydrogen atmosphere [J].
Francke, M ;
Hermann, H ;
Wenzel, R ;
Seifert, G ;
Wetzig, K .
CARBON, 2005, 43 (06) :1204-1212
[10]   Upper critical field and irreversibility line in superconducting MgB2 [J].
Fuchs, G ;
Müller, KH ;
Handstein, A ;
Nenkov, K ;
Narozhnyi, VN ;
Eckert, D ;
Wolf, M ;
Schultz, L .
SOLID STATE COMMUNICATIONS, 2001, 118 (10) :497-501