Chemistry of azoimidazoles. Synthesis, spectral characterization and redox studies of N(1)-benzyl-2-(arylazo)imidazolepalladium(II)chloride

被引：62

作者：

Das, D ^{[1
]}

Nayak, MK ^{[1
]}

Sinha, C ^{[1
]}

机构：

[1] UNIV BURDWAN GOLAPBAG,DEPT CHEM,BURDWAN 713104,W BENGAL,INDIA

来源：

TRANSITION METAL CHEMISTRY | 1997年 / 22卷 / 02期

关键词：

D O I：

10.1023/A:1018427432703

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Arylazoimidazoles (2) are N,N-chelating ligands. The polymerization trend of the azolate system is restricted via N(1)-benzylation. The parent molecules (2), N(1)-benzylated products (3) and palladium complexes (4) were made by standard methods. The ligands (3) and complexes (4) are new. They have been characterized by elemental analysis, i.r., u.v.-vis. and high resolution H-1-n.m.r. spectral data. Redox studies were carried out by cyclic voltammetry. On complexation, azo reduction is shifted anodically.

引用

页码：172 / 175

页数：4

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