Hydrogen bonding control of molecular self-assembly: Aggregation behavior of acylaminopyridine-carboxylic acid derivatives in solution and the solid state

被引：51

作者：

Zafar, A

Geib, SJ

Hamuro, Y

Carr, AJ

Hamilton, AD

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

[2] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA

来源：

TETRAHEDRON | 2000年 / 56卷 / 43期

基金：

美国国家科学基金会;

关键词：

self-assembly; hydrogen bonding; acylaminopyridine-carboxylic acid;

D O I：

10.1016/S0040-4020(00)00733-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this paper we report the design, synthesis and investigation of a family of acylaminopyridine-carboxylic acid monomers that can aggregate through bidentate hydrogen bonding interactions between the carboxylic acid and the aminopyridine sites. We show that in solution the nature of the aggregate depends on the substitution pattern of the monomer and present evidence from NMR and mass spectrometry that in some cases cyclic association occurs. (C) 2000 Elsevier Science Ltd. All rights reserved.

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收藏

页码：8419 / 8427

页数：9

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