High-throughput measurement of polymer blend phase behavior

被引:164
作者
Meredith, JC [1 ]
Karim, A [1 ]
Amis, EJ [1 ]
机构
[1] NIST, Div Polymers, Gaithersburg, MD 20899 USA
关键词
D O I
10.1021/ma0004662
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
High-throughput measurement of cloud points for polymer blend was carried out using a novel sample deposition method for creating two-dimensional composition (φ), temperature (T) libraries. In the sample libraries, T and φ were varied orthogonally, and optical microscopy was used to detect phase separation and microstructure. The cloud points determined with this high-throughput method were validated by comparison to conventional light scattering results and single-composition controls.
引用
收藏
页码:5760 / 5762
页数:3
相关论文
共 17 条
[1]  
BAUER BJ, 1989, POLYM COMMUN, V30, P19
[2]  
Bein T, 1999, ANGEW CHEM INT EDIT, V38, P323, DOI 10.1002/(SICI)1521-3773(19990201)38:3<323::AID-ANIE323>3.0.CO
[3]  
2-4
[4]  
Brocchini S, 1998, J BIOMED MATER RES, V42, P66, DOI 10.1002/(SICI)1097-4636(199810)42:1<66::AID-JBM9>3.0.CO
[5]  
2-M
[6]  
BUDTOV VP, 1967, POLYM SCI USSR, V9, P854
[7]   Materials a la combi [J].
Dagani, R .
CHEMICAL & ENGINEERING NEWS, 2000, 78 (20) :66-68
[8]   DYNAMIC LIGHT-SCATTERING AND PULSED GRADIENT SPIN-ECHO NMR MEASUREMENTS OF DIFFUSION IN POLYSTYRENE POLY(VINYL METHYL-ETHER) TOLUENE SOLUTIONS [J].
DAIVIS, PJ ;
PINDER, DN ;
CALLAGHAN, PT .
MACROMOLECULES, 1992, 25 (01) :170-178
[9]   A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods [J].
Danielson, E ;
Devenney, M ;
Giaquinta, DM ;
Golden, JH ;
Haushalter, RC ;
McFarland, EW ;
Poojary, DM ;
Reaves, CM ;
Weinberg, WH ;
Wu, XD .
SCIENCE, 1998, 279 (5352) :837-839
[10]   Generating sensor diversity through combinatorial polymer synthesis [J].
Dickinson, TA ;
Walt, DR ;
White, J ;
Kauer, JS .
ANALYTICAL CHEMISTRY, 1997, 69 (17) :3413-3418