Photocatalytic oxidation of 2,4-dichlorophenoxyacetic acid with titania photocatalyst.: Comparison of supported and suspended TiO2

被引:70
作者
Modestov, AD [1 ]
Lev, O [1 ]
机构
[1] Hebrew Univ Jerusalem, Fredy & Nadine Herrmann Sch Appl Sci, Div Environm Sci, IL-91904 Jerusalem, Israel
关键词
photodegradation; 2,4-D; titania; photocatalysis;
D O I
10.1016/S1010-6030(97)00269-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photodegradation of 2,4-dichlorophenoxyacetic acid using illuminated titania particles was studied in buffered water solutions at pH 9.2. A simplified phenomenological model which enables comparison of activity of suspended and supported photocatalyst on the basis of utilisation of light is proposed. The model shows saturation of photodegradation rate with increase of amount of photocatalyst on support or in suspension. The features of the model were verified by studies of the photocatalytic activity of TiO(2) suspended and supported on flat glass plate and on floating particles. (C) 1998 Elsevier Science S.A.
引用
收藏
页码:261 / 270
页数:10
相关论文
共 35 条
[1]  
Al-Ekabi H., 1989, PHOTOCATALYSIS FUNDA, P457
[2]   KINETIC-STUDIES IN HETEROGENEOUS PHOTOCATALYSIS .2. TIO2-MEDIATED DEGRADATION OF 4-CHLOROPHENOL ALONE AND IN A 3-COMPONENT MIXTURE OF 4-CHLOROPHENOL, 2,4-DICHLOROPHENOL, AND 2,4,5-TRICHLOROPHENOL IN AIR-EQUILIBRATED AQUEOUS-MEDIA [J].
ALEKABI, H ;
SERPONE, N ;
PELIZZETTI, E ;
MINERO, C ;
FOX, MA ;
DRAPER, RB .
LANGMUIR, 1989, 5 (01) :250-255
[3]   SEMICONDUCTOR-SENSITIZED PHOTODEGRADATION OF 4-CHLOROPHENOL IN WATER [J].
ALSAYYED, G ;
DOLIVEIRA, JC ;
PICHAT, P .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1991, 58 (01) :99-114
[4]  
BAHNEMANN DW, 1993, TR MET ENV, V3, P301
[5]   PHOTODEGRADATION OF PENTACHLOROPHENOL CATALYZED BY SEMICONDUCTOR PARTICLES [J].
BARBENI, M ;
PRAMAURO, E ;
PELIZZETTI, E ;
BORGARELLO, E ;
SERPONE, N .
CHEMOSPHERE, 1985, 14 (02) :195-208
[6]   SUNLIGHT PHOTODEGRADATION OF 2,4,5-TRICHLOROPHENOXY-ACETIC ACID AND 2,4,5,TRICHLOROPHENOL ON TIO2 - IDENTIFICATION OF INTERMEDIATES AND DEGRADATION PATHWAY [J].
BARBENI, M ;
MORELLO, M ;
PRAMAURO, E ;
PELIZZETTI, E ;
VINCENTI, M ;
BORGARELLO, E ;
SERPONE, N .
CHEMOSPHERE, 1987, 16 (06) :1165-1179
[7]  
Born M., 1975, Principles of Optics: Electromagnetic Theory of Propagation, Interference and Diffraction of Light, V5th
[9]  
GALVEZ JB, 1993, TR MET ENV, V3, P639
[10]   PHOTOCATALYTIC OXIDATION OF ORGANIC-MOLECULES AT TIO2 PARTICLES BY SUNLIGHT IN AERATED WATER [J].
GERISCHER, H ;
HELLER, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (01) :113-118