Improvement of dynamic gas sensing behavior of SnO2 acicular particles by microwave calcination

The CO response time of SnO2 acicular-particle-type gas sensors was shortened to a great extent using rapid microwave calcination. When SnO2 acicular particles were prepared by the slow heating (heating rate: 4.2 degrees C/min) of a SnC2O4 precursor to the calcination temperature (500 degrees C) using a conventional furnace, the 90% response time to 30 ppm CO (t(90%)(air-to-CO) was 76s at a sensing temperature of 450 degrees C. However, the t(90%) (air-to-CO) decreased markedly down to 5-27 s when the precursor was heated rapidly (heating rate: 25-100 degrees C/min) using a microwave furnace. The significant shortening of the response time was attributed to the formation of a mesoporous structure in the SnO2 acicular particles due to rapid gas evolution during the decomposition of the SnC2O4 precursor. (C) 2006 Elsevier B.V. All rights reserved.