One-step electrodeposition of platinum nanoflowers and their high efficient catalytic activity for methanol electro-oxidation

被引：116

作者：

Zhang, Hongmei ^{[1
]}

Zhou, Weiqiang ^{[1
]}

Du, Yukou ^{[1
]}

Yang, Ping ^{[1
]}

Wang, Chuanyi ^{[2
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

[2] Tufts Univ, Dept Chem, Medford, MA 02155 USA

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2010年 / 12卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Pt nanoflowers; Electrodeposition; Methanol; Fuel; Energy; Catalysis; SINGLE-CRYSTAL ELECTRODES; FUEL-CELL; HYDROGEN ADSORPTION; NANOWIRES; OXIDATION; NANOSTRUCTURES; POLYOL; ELECTROCATALYSTS; NANOPARTICLES; REDUCTION;

D O I：

10.1016/j.elecom.2010.04.011

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A facile, one-step and template-free electrodeposition method has been developed for the first time to prepare porous Pt nanoflowers. The flowerlike architectures were confirmed by SEM, and further structurally characterized by XRD and electrochemical analyses. Compared to conventional nanosized Pt catalysts, as-prepared Pt nanoflowers exhibit remarkably higher catalytic activity and stronger poisoning-tolerance for the methanol electro-oxidation, and thus they are anticipated to find interesting applications in many important fields such as energy and catalysis. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：882 / 885

页数：4

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