Synthesis, characterization and application of Ru(BINAP)(Acac)(MNAA)(MeOH), a highly effective catalyst for the asymmetric hydrogenation of 2-(6′-methoxynaphth-2′-yl)acrylic acid

被引：16

作者：

Chen, CC

Huang, TT

Lin, CW

Cao, R

Chan, ASC ^{[1
]}

Wong, WT

机构：

[1] Hong Kong Polytech Univ, Union Lab Asymmetr Synth, Hong Kong, Peoples R China

[2] Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China

[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 1998年 / 270卷 / 1-2期

关键词：

asymmetric hydrogenation; ruthenium complexes; BINAP complexes; acetylacetonate complexes; acrylate anion complexes;

D O I：

10.1016/S0020-1693(97)05850-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ru(S-BINAP) (Acac) (MNAA) (MeOH) (1) (where MNAA (2) = 2-(6'-methoxynaphth-2'-yl) acrylate anion), a highly effective catalyst for the asymmetric hydrogenation of 2-(6'-methoxynaphth-2'-yl) acrylic acid (3)!, was isolated from a dichloromethane/methanol (vol./vol. = 1/4) solution of Ru(S-BINAP) (Acac), and excess of 2-(6'-methoxynaphth-2'-yl)acrylic acid after the solution was exposed to visible light for 2 weeks. On side by side comparison studies, the rate of the hydrogenation of 3 catalyzed by 1 was found to be substantially faster than the same reaction catalyzed by Ru(S-BINAP) (OAc)(2). The molecular structure of 1 was unambiguously characterized by single crystal X-ray diffraction. (C) 1998 Elsevier Science S.A.

引用

页码：247 / 251

页数：5

共 20 条

[1]

[Anonymous], 1992, TEXSAN CRYST STRUCT

[2]

[Anonymous], ASYMMETRIC SYNTHESIS

[3]

[Anonymous], 1985, TEXSAN CRYST STRUCT

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF AN ASYMMETRIC HYDROGENATION CATALYST SUBSTRATE ADDUCT, DELTA-BIS(TIGLATO)((R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL)-RUTHENIUM(II), [RUII(BINAP)(O2CCME=CHME)2] [J].