Recent advances in the homogeneous hydrogenation of carbon dioxide

被引:612
作者
Jessop, PG [1 ]
Joó, F
Tai, CC
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Univ Debrecen, Inst Phys Chem, H-4010 Debrecen, Hungary
[3] Hungarian Acad Sci, Res Grp Homogeneous Catalysis, H-4010 Debrecen, Hungary
[4] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
基金
匈牙利科学研究基金会;
关键词
carbon dioxide; hydrogenation; formic acid; formamides; homogeneous catalysis;
D O I
10.1016/j.ccr.2004.05.019
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Homogeneous hydrogenation of carbon dioxide continues to attract interest in the hope of finding active and selective catalysts for the production of valuable organics based on this cheap and abundant carbon source. This review covers advances published or in press since 1995. The survey of the field shows that while very active catalysts and co-catalysts have been discovered in this period for the production of formic acid and its derivatives, there has been only preliminary development of homogeneous catalysts for the production of other oxygenates (e.g. methanol, CO) and C(n)-compounds (n > 1). (C) 2004 Elsevier B.V. All rights reserved.
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页码:2425 / 2442
页数:18
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