A novel type of alkynylgold(I) complex.: Crystal and molecular structures of PPN[Au(Ar)(C≡CH)] [Ar = C6F5, C6H2(NO2)3-2,4,6]

被引：21

作者：

Vicente, J

Chicote, MT

Abrisqueta, MD

Jones, PG

机构：

[1] Univ Murcia, Grp Quim Organomet, E-30071 Murcia, Spain

[2] Univ Murcia, Dept Quim Inorgan, E-30071 Murcia, Spain

[3] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 13期

关键词：

D O I：

10.1021/om9910322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the type PPN[Au(acac)(Ar)] [PPN = (Ph3P)(2)N, acac = acetylacetonate], obtained in solution from Tl(acac) and the corresponding PPN[Au(Ar)Cl] derivatives after removal of TlCl, react in situ with ethyne to give a new type of ethynylgold(I) complex, PPN[Au(Ar)(C drop CH)] [Ar = C6F5 (1), C6H4NO2-2 (2), C6H2(NO2)(3)-2,4,6(3)]. The crystal structures of 1 and 3 have been determined.

引用

收藏

页码：2629 / 2632

页数：4

相关论文

共 69 条

[1] THE REACTIVITY OF THE BIS(PHENYLETHYNYL)AURATE(I) COMPLEX ANION - SYNTHESIS AND CHARACTERIZATION OF NOVEL DI-NUCLEAR AND TRI-NUCLEAR GROUP IB METAL ARYLACETYLIDES [J].

ABUSALAH, OM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 270 (01) :C26-C28

[2] PREPARATION, IDENTIFICATION, AND REACTIVITY OF NEW ORGANOGOLD(I) HALIDE ANION COMPLEXES [J].

ABUSALAH, OM ;

ALOHALY, AR .

INORGANICA CHIMICA ACTA-LETTERS, 1983, 77 (04) :L159-L160

[3] YLIDE GOLD(I) COMPLEXES OF THE TYPES [AU(YLIDE)L]+, [AU(YLIDE)(CCR)] AND [AU(YLIDE)(CO(CO)4)] [J].

AGUIRRE, CJ ;

GIMENO, MC ;

LAGUNA, A ;

LAGUNA, M ;

DELUZURIAGA, JML ;

PUENTE, F .

INORGANICA CHIMICA ACTA, 1993, 208 (01) :31-36

[4]

ALEJOS P, 1995, NEW J CHEM, V19, P799

[5] AN APPRAISAL OF VALENCE-BOND STRUCTURES AND HYBRIDIZATION IN COMPOUNDS OF THE 1ST-ROW ELEMENTS [J].

BENT, HA .

CHEMICAL REVIEWS, 1961, 61 (03) :275-311

[6] REACTIONS OF (TERTIARY PHOSPHINE)GOLD(I) SUBSTITUTED IMIDAZOLES OR PYRAZOLONES WITH ACIDIC REAGENTS - PROTONATION, AZOLE DISPLACEMENT, AND ADDUCT FORMATION - CRYSTAL-STRUCTURE DETERMINATION OF THE ADDUCT 1-METHYL-2-(CYCLOHEXYLPHOSPHINEGOLDTHIOLATO)IMIDAZOLE.2BENZIMIDAZOLE [J].

BONATI, F ;

BURINI, A ;

PIETRONI, BR ;

GIORGINI, E ;

BOVIO, B .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 344 (01) :119-135

[7] REACTIONS OF [AU(C6F5)(SC4H8)] WITH DIAZOALKANES - SYNTHESIS AND MOLECULAR-STRUCTURES OF [AU(C6F5)(PH2C=N-N=CPH2)] [J].

BORDONI, S ;

BUSETTO, L ;

CASSANI, MC ;

ALBANO, VG ;

SABATINO, P .

INORGANICA CHIMICA ACTA, 1994, 222 (1-2) :267-273

[8] CHEMISTRY OF THE GROUP-1B METALS .17. PREPARATION OF SOME GOLD(I) ACETYLIDE COMPLEXES CONTAINING GROUP-5 DONOR LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF AU(C2C6F5)(PPH3) [J].

BRUCE, MI ;

HORN, E ;

MATISONS, JG ;

SNOW, MR .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (06) :1163-1170

[9] INCLUSION AND AGGREGATION PROPERTIES OF ORGANOGOLD COMPLEXES - CRYSTAL-STRUCTURES OF C2(AU[P(C6H4R-3)3])2.NC6H6(R = H, N = 2-R = ME, N = 0 AND 1) [J].

BRUCE, MI ;

GRUNDY, KR ;

LIDDELL, MJ ;

SNOW, MR ;

TIEKINK, ERT .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 344 (03) :C49-C52

[10] CHEMISTRY OF THE GROUP-1B METALS .19. CRYSTAL AND MOLECULAR-STRUCTURES OF (2-PHENYLETHYNYL)(TRIPHENYLPHOSPHINE)GOLD(I), AU(C=CPH)(PPH3) [J].

BRUCE, MI ;

DUFFY, DN .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1986, 39 (10) :1697-1701

← 1 2 3 4 5 6 7 →