Effect of solutes on single-bubble sonoluminescence in water

被引:69
作者
Ashokkumar, M
Crum, LA
Frensley, CA
Grieser, F [1 ]
Matula, TJ
McNamara, WB
Suslick, KS
机构
[1] Univ Melbourne, Sch Chem, Particulate Fluids Proc Ctr, Parkville, Vic 3010, Australia
[2] Univ Washington, Appl Phys Lab, Seattle, WA 98105 USA
[3] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA
关键词
D O I
10.1021/jp000463r
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Low concentrations of short chain aliphatic alcohols and organic acids and bases suppress single-bubble sonoluminescence (SBSL) in water. The degree of SL quenching increases with the length of the aliphatic end of the alcohol, and is related to the concentration of the alcohol at the bubble/water interface. The light is preferentially quenched in the shorter wavelength region of the spectrum. Radius-time measurements of the bubble are not dramatically affected by the low levels of alcohol used. Butyric acid and propylamine behave in the same manner, but only in their neutral forms, indicating that the SBSL suppression is due to processes occurring within the bubble.
引用
收藏
页码:8462 / 8465
页数:4
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