Oxidation of aromatic substrates in water/goethite slurry by means of hydrogen peroxide

被引：92

作者：

Andreozzi, R ^{[1
]}

D'Apuzzo, A ^{[1
]}

Marotta, R ^{[1
]}

机构：

[1] Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy

来源：

WATER RESEARCH | 2002年 / 36卷 / 19期

关键词：

goethite; hydrogen peroxide; fenton-like reactions; chemical oxidation; kinetics; phenolic compounds;

D O I：

10.1016/S0043-1354(02)00204-X

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The oxidation of aromatic derivatives in aqueous goethite slurry at varying catalyst load and hydrogen peroxide concentration is investigated. For,adopted experimental conditions only the compounds containing two adjacent -OH groups or one -OH and one -NH2 groups are oxidized. A model previously developed for the oxidation of 3,4dihydroxybenzoic acid has been satisfactorily used to describe the oxidation of 1,2-benzenediol (catechol), 2-aminophenol and 2,3-dihydroxybenzoic acid. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4691 / 4698

页数：8

共 20 条

[1] ANDREOZZI R, 2002, IN PRESS WATER RES
[2] [Anonymous], 1983, ENG OPTIMIZATION
[3] PHOTOMETRIC-METHOD FOR THE DETERMINATION OF LOW CONCENTRATIONS OF HYDROGEN-PEROXIDE BY THE PEROXIDASE CATALYZED OXIDATION OF N,N-DIETHYL-P-PHENYLENEDIAMINE (DPD)
BADER, H
STURZENEGGER, V
HOIGNE, J
[J]. WATER RESEARCH, 1988, 22 (09) : 1109 - 1115
[4] Bird R.B., 2006, TRANSPORT PHENOMENA, Vsecond, DOI 10.1002/aic.690070245
[5] Influence of structural features on sorption of NOM-analogue organic acids to goethite
Evanko, CR
Dzombak, DA
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1998, 32 (19) : 2846 - 2855
[6] LANGE NA, 1967, LANGES HDB CHEM, P1211
[7] RESORCINOL, CATECHOL AND HYDROQUINONE BIODEGRADATION IN MONO AND BINARY SUBSTRATE MATRICES IN UPFLOW ANAEROBIC FIXED-FILM FIXED-BED REACTORS
LATKAR, M
CHAKRABARTI, T
[J]. WATER RESEARCH, 1994, 28 (03) : 599 - 607
[8] Levenspiel O., 1972, CHEM ENG REACTION
[9] Catalytic decomposition of hydrogen peroxide on iron oxide: Kinetics, mechanism, and implications
Lin, SS
Gurol, MD
[J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1998, 32 (10) : 1417 - 1423
[10] Heterogeneous catalytic oxidation of organic compounds by hydrogen peroxide
Lin, SS
Gurol, MD
[J]. WATER SCIENCE AND TECHNOLOGY, 1996, 34 (09) : 57 - 64

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