CoII5(OH)6(SO4)2(H2O)4:: the first ferromagnet based on a layered cobalt-hydroxide pillared by inorganic•••OSO3-Co(H2O)4-O3SO•••

被引：15

作者：

Ben Salah, M

Vilminot, S

Richard-Plouet, M

André, G

Mhiri, T

Kurmoo, M

机构：

[1] ULP, CNRS, UMR 7504,IPCMS, Grp Mat Inorgan, F-67034 Strasbourg, France

[2] CNRS, UMR 6502, Lab Chim Solides, Inst Mat Jean Rouxel, F-44322 Nantes 03, France

[3] CEA Saclay, CNRS, CEA, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France

[4] Fac Sci, Lab Etat Solide, Sfax 3038, Tunisia

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 22期

关键词：

D O I：

10.1039/b411304g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic mineral Co-5(II)(OH)(6)(SO4)(2)(H2O)(4) ( 1), obtained by hydrothermal reaction of CoSO4.7H(2)O and NaOH at 165 degreesC and consisting of brucite-like Co-4(OH)(6)O-2 layers pillared by OSO3 - Co(H2O)(4) - O3SO, is a ferromagnet (T-Curie = 12 K, H-c = 580 Oe).

引用

页码：2548 / 2549

页数：2

共 24 条

[1] Synthesis, nuclear, and magnetic structures and magnetic properties of [Mn3(OH)2(SO4)2(H2O)2] [J].