Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity

被引：646

作者：

Zeng, Ming-Hua ^{[1
]}

Wang, Qiang-Xin ^{[1
]}

Tan, Yan-Xi ^{[1
]}

Hu, Sheng ^{[1
]}

Zhao, Hai-Xia ^{[2
,3
]}

Long, La-Sheng ^{[2
,3
]}

Kurmoo, Mohamedally ^{[4
]}

机构：

[1] Guangxi Normal Univ, Key Lab Chem & Mol Engn Med Resources, Minist Educ, Sch Chem & Chem Engn, Guilin 541004, Peoples R China

[2] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Peoples R China

[3] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[4] Univ Strasbourg, Chim Coordinat Organ Lab, CNRS, UMR7140, F-67000 Strasbourg, France

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 08期

关键词：

COORDINATION POLYMER; DIAMOND FRAMEWORK; GUEST-EXCHANGE; ADSORPTION; MOLECULES; CHANNELS; INCLUSION; ROBUST; STATE;

D O I：

10.1021/ja908293n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly stable pillared and double-walled zinc(II) metal-organic framework with regular nanochannels displays single-crystal to single-crystal transformation upon desolvation and a large quantity of iodine uptake, controlled release, and electrical conductivity elevation due to synergy between the iodine guests and the host framework.

引用

页码：2561 / +

页数：4

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