Elucidation of the chain conformation in a glassy polyester, PET, by two-dimensional NMR

The chain conformation of glassy poly(ethylene terephthalate) (PET) was characterized by two-dimensional double-quantum nuclear magnetic resonance (NMR). In amorphous carbon-13-labeled PET, the statistics of the O-(CH2)-C-13-(CH2)-C-13-O torsion angle were determined, on the basis of the distinct shapes of the two-dimensional MMR patterns of trans and gauche conformations. In crystalline PET, the trans content is 100 percent, but in the amorphous PET it is only 14 percent (+/-5 percent). An average gauche torsion angle of 70 degrees (+/-9 degrees) was obtained. Implications for materials properties of polyesters are discussed.