Development of Ni/Y2O3-ZrO2 cermet anodes for solid oxide fuel cells

被引:51
作者
Jiang, SP [1 ]
Chan, SH [1 ]
机构
[1] Nanyang Technol Univ, Sch Mech & Prod Engn, Fuel Cell Strateg Res Programme, Singapore 639798, Singapore
关键词
solid oxide fuel cells; cemet anodes; yttrium oxides; zirconium oxides;
D O I
10.1179/026708304225019957
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ni/Y2O3-ZrO2 (Ni/YSZ) cermets are the most common anode materials for high temperature solid oxide fuel cells (SOFC). Electrode performance of Ni/YSZ cermets is critically dependent on the microstructure and distribution of Ni and YSZ phases in the cermets. This in turn is closely related to the characteristics of the NiO and YSZ powders, and the fabrication process. The objective of this paper is to discuss some important issues associated with the fabrication and development of Ni/Y2O3-ZrO2 anode materials for SOFC from the viewpoint of materials science and technology. Results indicate that the optimisation of Ni/YSZ cermet anodes is a complicated process and understanding of the H-2 oxidation reaction is also very important in the development of high performance Ni/YSZ cermet anodes.
引用
收藏
页码:1109 / 1118
页数:10
相关论文
共 60 条
[1]  
Badwal S.P.S., 1997, Mater. Forum, V21, P187
[2]   The electrochemistry of Ni pattern anodes used as solid oxide fuel cell model electrodes [J].
Bieberle, A ;
Meier, LP ;
Gauckler, LJ .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (06) :A646-A656
[3]   Structure/performance relations for Ni/yttria-stabilized zirconia anodes for solid oxide fuel cells [J].
Brown, M ;
Primdahl, S ;
Mogensen, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (02) :475-485
[4]  
Carrette L, 2001, FUEL CELLS, V1, P5, DOI 10.1002/1615-6854(200105)1:1<5::AID-FUCE5>3.0.CO
[5]  
2-G
[6]   Anode micro model of solid oxide fuel cell [J].
Chan, SH ;
Xia, ZT .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (04) :A388-A394
[7]   Reliability and accuracy of measured overpotential in a three-electrode fuel cell system [J].
Chan, SH ;
Chen, XJ ;
Khor, KA .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (10) :1163-1170
[8]   SINTERING AND CHARACTERIZATION OF POLYCRYSTALLINE MONOCLINIC, TETRAGONAL, AND CUBIC ZIRCONIA [J].
CUTLER, RA ;
REYNOLDS, JR ;
JONES, A .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (08) :2173-2183
[9]   The effect of the presence of fine YSZ particles on the performance of porous nickel electrodes [J].
de Boer, B ;
Gonzalez, M ;
Bouwmeester, HJM ;
Verweij, H .
SOLID STATE IONICS, 2000, 127 (3-4) :269-276
[10]   Performance and stability of SOFC anode fabricated from NiO-YSZ composite particles [J].
Fukui, T ;
Ohara, S ;
Naito, M ;
Nogi, K .
JOURNAL OF POWER SOURCES, 2002, 110 (01) :91-95