Prussian White as a highly active molecular catalyst for proton reduction

被引：30

作者：

Abe, T

Taguchi, F

Tokita, S

Kaneko, M

机构：

[1] Ibaraki Univ, Fac Sci, Mito, Ibaraki 310, Japan

[2] Saitama Univ, Fac Engn, Urawa, Saitama 338, Japan

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 126卷 / 2-3期

关键词：

proton reduction; molecular catalyst; Prussian White;

D O I：

10.1016/S1381-1169(97)00156-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrocatalytic H+ reduction was found with the polynuclear iron-cyanide complex called Prussian White (PW, K4Fe4II[Fe-II(CN)(6)](3)) coated on a Pt electrode. The PW-coated Pt produced much larger amounts of H-2 than a bare electrode even at the theoretical potential of H+/H-2. Its electrocatalytic activity exceeded the conventional Pt catalyst. (C) 1997 Elsevier Science B.V.

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收藏

页码：L89 / L92

页数：4

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