Graphite polyhedral crystals

被引:189
作者
Gogotsi, Y
Libera, JA
Kalashnikov, N
Yoshimura, M
机构
[1] Univ Illinois, Dept Mech Engn, Chicago, IL 60607 USA
[2] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 226, Japan
关键词
D O I
10.1126/science.290.5490.317
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Polyhedral nano- and microstructures with shapes of faceted needles, rods, rings, barrels, and double-tipped pyramids, which we call graphite polyhedral crystals (GPCs), have been discovered. They were found in pores of glassy carbon. They have nanotube cores and graphite faces, and they can exhibit unusual sevenfold, ninefold, or more complex axial symmetry. Although some are giant radially extended nanotubes, Raman spectroscopy and transmission electron microscopy suggest GPCs have a degree of perfection higher than in multiwall nanotubes of similar size. The crystals are up to 1 micrometer in cross section and 5 micrometers in Length, and they can probably be grown in much Larger sires. Preliminary results suggest a high electrical conductivity, strength, and chemical stability of GPC.
引用
收藏
页码:317 / 320
页数:4
相关论文
共 24 条
  • [1] Ajayan P. M., 1997, CARBON NANOTUBES PRE, P111
  • [2] GROWTH, STRUCTURE, AND PROPERTIES OF GRAPHITE WHISKERS
    BACON, R
    [J]. JOURNAL OF APPLIED PHYSICS, 1960, 31 (02) : 283 - 290
  • [3] GROWTH OF CARBON NANOTUBES - A MOLECULAR-DYNAMICS STUDY
    BRABEC, CJ
    MAITI, A
    ROLAND, C
    BERNHOLC, J
    [J]. CHEMICAL PHYSICS LETTERS, 1995, 236 (1-2) : 150 - 155
  • [4] Dresselhaus M. S., 1996, SCI FULLERENES CARBO
  • [5] Dresselhaus M.S., 1999, ANAL APPL RAMAN SPEC, P367
  • [6] Carbon nanotubes
    Ebbesen, TW
    [J]. PHYSICS TODAY, 1996, 49 (06) : 26 - 32
  • [7] ENDO M, 1997, CARBON NANOTUBES PRE, P35
  • [8] OXIDATION RESISTANCE OF BORON CARBIDE-BASED CERAMICS
    GOGOTSI, YG
    YAROSHENKO, VP
    PORZ, F
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 1992, 11 (05) : 308 - 310
  • [9] A TEST OBJECT AND CRITERIA FOR HIGH RESOLUTIONELECTRON MICROSCOPY
    HEIDENRE.RD
    HESS, WM
    BAN, LL
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1968, 1 : 1 - &
  • [10] RAMAN STUDIES OF CARBON NANOTUBES
    HIURA, H
    EBBESEN, TW
    TANIGAKI, K
    TAKAHASHI, H
    [J]. CHEMICAL PHYSICS LETTERS, 1993, 202 (06) : 509 - 512