Synthesis and characterization of cross-linked reverse micelles

被引：69

作者：

Jung, HM ^{[1
]}

Price, KE ^{[1
]}

McQuade, DT ^{[1
]}

机构：

[1] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 18期

关键词：

D O I：

10.1021/ja0271983

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The design and synthesis of a new cross-linkable amphiphile is reported. Solutions of the amphiphile in a toluene/water mixture form reverse micelles as indicated by dynamic light scattering and NMR spectroscopy. As indicated by dynamic light scattering, TEM, and NMR spectroscopy data, these reverse micelles can be cross-linked without drastically changing the radius of the reverse micelles. Mixed reverse micelles are also characterized and cross-linked. The cross-linked reverse micelles are demonstrated to facilitate phase transfer and can be used to site isolate a catalyst.

引用

页码：5351 / 5355

页数：5

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