Sensitized fluorescence of Ce3+/Mn2+ system in phosphate glass

被引：776

作者：

Paulose, PI

Jose, G

Thomas, V

Unnikrishnan, NV

Warrier, MKR

机构：

[1] Mahatma Gandhi Univ, Sch Pure & Appl Phys, Kottayam 686560, India

[2] Maharajas Coll, Res Ctr, Ernakulam 682011, India

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 2003年 / 64卷 / 05期

关键词：

glasses; optical materials; luminescence; optical properties;

D O I：

10.1016/S0022-3697(02)00416-X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of sodium phosphate glasses singly and doubly doped with rare earth ion Ce3+ and transition metal ion Mn2+ by a melt quench method is described. The spectroscopic characterizations of the samples are conducted by absorption, excitation, and emission spectra. The orange red emission of divalent manganese sensitized by trivalent cerium ions in a phosphate glassy matrix has been investigated. Energy transfer (ET) from optically excited Ce3+ to Mn2+ in sodium phosphate glass, by nonradiative process is confirmed by fluorescence studies with various activator concentrations. The mechanism of ET is mainly electric dipole-dipole in nature. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：841 / 846

页数：6

共 30 条

[1] Ce3+ or Tb3+-doped phosphate and silicate scintillating glasses [J].