Intramolecular addition of vinyl radicals to aldehydes

被引：28

作者：

Devin, P ^{[1
]}

Fensterbank, L ^{[1
]}

Malacria, M ^{[1
]}

机构：

[1] Univ Paris 06, CNRS, Lab Chim Organ & Synth, F-75252 Paris, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(97)10743-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of aldehydes 1 and 10 with Bu3SnH has been studied. In thermal conditions, after an initial chemoselective 6-exo-trig or 5-exo-trig cyclization to the aldehyde, a beta-scission reaction takes place, providing rearrangement products. At low temperature, using the Et3B/O-2 procedure, satisfactory yields of cyclohexanol 2 and cyclopentanol 11 are obtained. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：833 / 836

页数：4

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