Direct thermal intercalation of amine into layered MoO3

被引：38

作者：

Jing, Yi ^{[1
]}

Pan, Qingyi ^{[1
]}

Cheng, Zhixuan ^{[1
]}

Dong, Xiaowen ^{[1
]}

Xiang, Yixian ^{[1
]}

机构：

[1] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China

来源：

MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2007年 / 138卷 / 01期

关键词：

molybdenum trioxide; intercalation; layered material; amine;

D O I：

10.1016/j.mseb.2007.01.015

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Molybdenum oxide nanocomposites with layered structures were prepared directly from commercial bulk MoO3 using alkylamines as the guests. By using molybdenum oxide-amines as the starting materials, novel molybdenum oxide-dye composite was synthesized. On the basis of X-ray diffraction, scanning electron microscopy and infrared results, a possible arrangement of alkylamines guests in the interlayer space of molybdenum oxide has been proposed. Moreover, the interactions between the inorganic host and the organic guests have been discussed. A linear relationship is observed between the interlayer distance and the number of carbon atoms in n-alkyl chains. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：55 / 59

页数：5

共 23 条

[1] SHAPE-SELECTIVE INTERCALATION REACTIONS OF LAYERED ZINC AND COBALT PHOSPHONATES [J].

CAO, G ;

MALLOUK, TE .

INORGANIC CHEMISTRY, 1991, 30 (07) :1434-1438

[2] Photomechanical response of azobenzene/organophilic mica complexes [J].

Fujita, T ;

Iyi, N ;

Klapyta, Z ;

Fujii, K ;

Kaneko, Y ;

Kitamura, K .

MATERIALS RESEARCH BULLETIN, 2003, 38 (15) :2009-2017

[3] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O [J].

Hagrman, D ;

Zubieta, C ;

Rose, DJ ;

Zubieta, J ;

Haushalter, RC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08) :873-876

[4] Synthesis of polypyrrole/MoO3 hybrid thin films and their volatile organic compound gas-sensing properties [J].

Hosono, K ;

Matsubara, I ;

Murayama, N ;

Woosuck, S ;

Izu, N .

CHEMISTRY OF MATERIALS, 2005, 17 (02) :349-354

[5] Intercalation of cationic azobenzene derivatives in a synthetic mica and their photoresponse [J].

Iyi, N ;

Fujita, T ;

Yelamaggad, CV ;

Arbeloa, FL .

APPLIED CLAY SCIENCE, 2001, 19 (1-6) :47-58

[6] Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors [J].

Kagan, CR ;

Mitzi, DB ;

Dimitrakopoulos, CD .

SCIENCE, 1999, 286 (5441) :945-947

[7] Concurrent polymerization and insertion of aniline in molybdenum trioxide: Formation and properties of a [poly(aniline)]0.24MoO3 nanocomposite [J].

Kerr, TA ;

Wu, H ;

Nazar, LF .

CHEMISTRY OF MATERIALS, 1996, 8 (08) :2005-2015

[8] Surfactant-mediated incorporation of poly(p-phenylene) into MoO3 [J].

Kerr, TA ;

Leroux, F ;

Nazar, LF .

CHEMISTRY OF MATERIALS, 1998, 10 (10) :2588-2591

[9] Intercalation of organic dyes in the layered host lattice V2O5 [J].

Kuwahara, T ;

Tagaya, H ;

Kadokawa, J .

INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (02) :63-65

[10] Synthesis and characterization of novel nanoscopic molybdenum oxide fibers [J].

Niederberger, M ;

Krumeich, F ;

Muhr, HJ ;

Müller, M ;

Nesper, R .

JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (07) :1941-1945

← 1 2 3 →