Either γ-syn- or γ-anti-selective palladium-catalysed carbonyl allylation by mixed (E)- and (Z)-1,3-dichloropropene with tin(II) halides

被引：23

作者：

Masuyama, Y ^{[1
]}

Ito, A ^{[1
]}

Kurusu, Y ^{[1
]}

机构：

[1] Sophia Univ, Dept Chem, Chiyoda Ku, Tokyo 102, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a707865j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium-catalysed carbonyl allylations by mixed (E)- and (Z)-1,3-dichloropropene with SnI2-Bu4NI and SnCI2 diastereoselectively produce syn and anti 1-substituted 2-chlorobut-3-en-1-ols, respectively. These are transformed into cis and trans 1-substituted 2-vinyl epoxides.

引用

页码：315 / 316

页数：2

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