Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems

被引：80

作者：

Grotzinger, C ^{[1
]}

Burget, D ^{[1
]}

Jacques, P ^{[1
]}

Fouassier, JP ^{[1
]}

机构：

[1] Ecole Natl Super Chim, Dept Photochim Gen, UMR 7525, CNRS, F-68093 Mulhouse, France

来源：

POLYMER | 2003年 / 44卷 / 13期

关键词：

photoinitiator; photopolymerization; dye;

D O I：

10.1016/S0032-3861(03)00286-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The activity of six newly designed three-component systems (containing a dye, an amine and a triazine derivative) for the initiation of the photopolymerization of multifunctional acrylates under visible light has been evaluated. The selection of the dyes was based on thermodynamic considerations. A discussion of the photochemical reactivity of these systems reveals the role played by thermodynamics and outlines different aspects concerned with kinetics. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3671 / 3677

页数：7

共 49 条

[1] Allonas X., 2001, POLYM PREPR AM CHEM, V42, P805
[2] [Anonymous], 1995, PHOTOINITIATION PHOT
[3] The excited states quenching of safranine T by p-benzoquinones in polar solvents
Bertolotti, SG
Previtali, CM
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 103 (1-2) : 115 - 119
[4] Burget D, 1999, ACTA POLYM, V50, P337, DOI 10.1002/(SICI)1521-4044(19990901)50:9<337::AID-APOL337>3.3.CO
[5] 2-9
[6] BURGET D, 2000, P RADTECH N AM, P386
[7] CATILAZ L, 1993, PCT INT APPL WO, V93, P15440
[8] Catilaz-Simonin L, 2001, J APPL POLYM SCI, V79, P1911, DOI 10.1002/1097-4628(20010307)79:10<1911::AID-APP200>3.0.CO
[9] 2-#
[10] Chen YH, 1997, J IMAGING SCI TECHN, V41, P178

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