The effect of Al/Pt interface reaction on lead-zirconate-titanate capacitor and the optimization of via contact for double metal ferroelectric RAM

被引:7
作者
Hwang, YS [1 ]
Lee, JW [1 ]
Lee, SY [1 ]
Koo, BJ [1 ]
Jung, DJ [1 ]
Chun, YS [1 ]
Lee, MH [1 ]
Shin, DW [1 ]
Shin, SH [1 ]
Lee, SE [1 ]
Kim, BH [1 ]
Kang, NS [1 ]
Kim, KN [1 ]
机构
[1] Samsung Elect Co, Semicond R&D Ctr, Technol Dev, Yongin City, Kyungki Do, South Korea
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1998年 / 37卷 / 3B期
关键词
FeRAM; PZT; via contact; Schottky barrier; Pt/Al; diffusion barrier;
D O I
10.1143/JJAP.37.1332
中图分类号
O59 [应用物理学];
学科分类号
摘要
The effect of the platinum and aluminum interface reaction on the capacitor properties were investigated in 64 k ferroelectric random access memory (RAM). Aluminum diffused into platinum and reacted to form an intermetallic compound during the post-anneal when aluminum had direct contact with the top platinum layer of the ferroelectric capacitor. The Al/Pt/PZT contact was chanced into an Al-Pt and lead-zirconate-titanate contact by the reaction. As a result, ferroelectric properties degraded and the leakage current of the top electrode and lead-zirconate-tianate contact started to increase after annealing at 300 degrees C. The capacitor structure was destroyed by the volume expansion due to the Al/Pt reaction at 400 degrees C. To prevent this reaction, a TiN layer was introduced as the barrier layer. This contact scheme showed no breakdown of the ferroelectric capacitor up to 400 degrees C which indicated that TiN acts as a good diffusion barrier for the double-metal process.
引用
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页码:1332 / 1335
页数:4
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