Enhanced effect of mesoporous silica on base-catalyzed aldol reaction

被引：70

作者：

Kubota, Y ^{[1
]}

Goto, K

Miyata, S

Goto, Y

Fukushima, Y

Sugi, Y

机构：

[1] Gifu Univ, Fac Engn, Dept Mat Sci & Technol, Gifu 5011193, Japan

[2] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 03期

关键词：

D O I：

10.1246/cl.2003.234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aldol reaction of 4-nitrobenzaldehyde with acetone gives 4(4-nitrophenyl)-4-hydroxy-2-butanone in high yield in the presence of both secondary amine and mesoporous silica, whereas the yield is low in the absence of the mesoporous silica.

引用

页码：234 / 235

页数：2

共 19 条

[1] AMINO-GROUPS IMMOBILIZED ON SILICA-GEL - AN EFFICIENT AND REUSABLE HETEROGENEOUS CATALYST FOR THE KNOEVENAGEL CONDENSATION
ANGELETTI, E
CANEPA, C
MARTINETTI, G
VENTURELLO, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1989, (01): : 105 - 107
[2] STUDIES ON MESOPOROUS MATERIALS .1. SYNTHESIS AND CHARACTERIZATION OF MCM-41
CHEN, CY
LI, HX
DAVIS, ME
[J]. MICROPOROUS MATERIALS, 1993, 2 (01): : 17 - 26
[3] Knoevenagel and aldol condensations catalysed by a new diamino-functionalised mesoporous material
Choudary, BM
Kantam, ML
Sreekanth, P
Bandopadhyay, T
Figueras, F
Tuel, A
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 142 (03) : 361 - 365
[4] HATTORI H, 1993, CHEM REV, V95, P5375
[5] Syntheses of highly ordered mesoporous materials, FSM-16, derived from kanemite
Inagaki, S
Koiwai, A
Suzuki, N
Fukushima, Y
Kuroda, K
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (05) : 1449 - 1457
[6] SYNTHESIS OF HIGHLY ORDERED MESOPOROUS MATERIALS FROM A LAYERED POLYSILICATE
INAGAKI, S
FUKUSHIMA, Y
KURODA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) : 680 - 682
[7] New basic mesoporous silica catalyst obtained by ammonia grafting
Inaki, Y
Kajita, Y
Yoshida, H
Ito, K
Hattori, T
[J]. CHEMICAL COMMUNICATIONS, 2001, (22) : 2358 - 2359
[8] Kantam ML, 1998, CHEM COMMUN, P1033
[9] BASE AND ACID CATALYSIS BY THE ALKALI-CONTAINING MCM-41 MESOPOROUS MOLECULAR-SIEVE
KLOETSTRA, KR
VANBEKKUM, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) : 1005 - 1006
[10] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM
KRESGE, CT
LEONOWICZ, ME
ROTH, WJ
VARTULI, JC
BECK, JS
[J]. NATURE, 1992, 359 (6397) : 710 - 712

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