Dry reforming of coke oven gases over activated carbon to produce syngas for methanol synthesis

被引：111

作者：

Bermudez, J. M. ^{[1
]}

Fidalgo, B. ^{[1
]}

Arenillas, A. ^{[1
]}

Menendez, J. A. ^{[1
]}

机构：

[1] CSIC, Inst Nacl Carbon, E-33080 Oviedo, Spain

来源：

FUEL | 2010年 / 89卷 / 10期

关键词：

Coke oven gas; Dry reforming; Syngas; Methanol; HYDROGEN-PRODUCTION; PARTIAL OXIDATION; STEAM; CATALYST; RECOVERY;

D O I：

10.1016/j.fuel.2010.01.014

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

The dry reforming of coke oven gases (COG) over an activated carbon used as catalyst has been studied in order to produce a syngas suitable for methanol synthesis. The primary aim of this work was to study the influence of the high amount of hydrogen present in the COG on the process of dry reforming, as well as the influence of other operation conditions, such us temperature and volumetric hourly space velocity (VHSV). It was found that the reverse water gas shift (RWGS) reaction takes place due to the hydrogen present in the COG, and that its influence on the process increases as the temperature decreases. This situation may give rise to the consumption of the hydrogen present in the COG, and the consequent formation of a syngas which is inappropriate for the synthesis of methanol. This reaction can be avoided by working at high temperatures (about 1000 degrees C) in order to produce a syngas that is suitable for methanol synthesis. It was also found that the RWGS reaction is favoured by an increase in the VHSV. In addition, the active carbon FY5 was proven to be an adequate catalyst for the production of syngas from COG. (c) 2010 Elsevier Ltd. All rights reserved.

引用

页码：2897 / 2902

页数：6

共 25 条

[1]

ASP B, 2007, THESIS LULEA U TECHN

[2] Biogas to syngas by microwave-assisted dry reforming in the presence of char [J].