Palladium-Catalyzed Allylic Acyloxylation of Terminal Alkenes in the Presence of a Base

被引：67

作者：

Thiery, Emilie ^{[1
]}

Aouf, Chahinez ^{[1
]}

Belloy, Julien ^{[1
]}

Harakat, Dominique ^{[1
]}

Le Bras, Jean ^{[1
]}

Muzart, Jacques ^{[1
]}

机构：

[1] Univ Reims, Inst Chim Mol Reims, UMR6229, CNRS,UFR Sci Exactes & Nat, F-51687 Reims 2, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 05期

关键词：

IONIZATION MASS-SPECTROMETRY; C-H OXIDATION; HYDROCARBON OXIDATION; MECHANISTIC INVESTIGATIONS; HYDROGEN-PEROXIDE; MOLECULAR-OXYGEN; OLEFINS; COMPLEXES; ACETATE; BOND;

D O I：

10.1021/jo902587u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The efficiency and the selectivity of the Pd-catalyzed oxidation, in carboxylic acids, of terminal alkenes are strongly improved ill the presence of a base. The methodology IS particularly Well adapted for the oxidation homoallylic alcohols, for which the resulting acyloxylated products are obtained selectively as E-isomers in fair to good yields.

引用

页码：1771 / 1774

页数：4

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