Steric and electronic effects in metallophilic double salts

被引:87
作者
Doerrer, Linda H. [1 ]
机构
[1] Boston Univ, Dept Chem, Boston, MA 02215 USA
基金
美国国家科学基金会;
关键词
METAL-METAL INTERACTIONS; MAGNUS GREEN SALT; ALPHA-DIIMINE LIGANDS; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURES; PLATINUM(II) COMPLEXES; BONDING RELATIONSHIPS; GOLD(I) COMPLEXES; CHAIN COMPOUNDS; BINUCLEAR;
D O I
10.1039/b920389c
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
This Perspective highlights our efforts to assemble infinite chains of metal atoms in double salts of the form [M](+)[M](-) under the complementary influences of metallophilic interactions and electrostatic attraction. Our design strategy necessarily incorporates the significant steric constraints of one-dimensional assemblies as well as the more subtle and challenging electronic tuning of weak dispersion forces.
引用
收藏
页码:3543 / 3553
页数:11
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