Synthesis and structural characterization of the mixed ligand complex [Cu(HmL)2(phen)] • 2H2O (H2mL=2-methyllactic acid)

被引：7

作者：

Carballo, R ^{[1
]}

Covelo, B

Vázquez-López, EM

Castiñeiras, A

Niclós, J

机构：

[1] Univ Vigo, Dept Quim Inorgan, Fac Ciencias, E-36200 Vigo, Galicia, Spain

[2] Univ Santiago de Compostela, Dept Quim Inorgan, Fac Farm, E-15782 Santiago De Compostela, Galicia, Spain

[3] Univ Granada, Fac Ciencias, Dept Quim Inorgan, E-18071 Granada, Spain

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2003年 / 58卷 / 2-3期

关键词：

copper(II); 2-methyllactic acid; phenanthroline;

D O I：

10.1515/znb-2003-0122

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new mixed-ligand complex of copper(II) with 1,10-phenanthroline and 2-methyllactate was prepared. [Cu(HmL)(2)(phen)].2H(2)O (where HmL = monodeprotonated 2-methyllactic acid) was characterized by elemental analysis, IR, electronic and EPR spectroscopy, magnetic measurements at room temperature, thermogravimetric analysis and X-ray diffractometry. The copper atom is in a tetragonally distorted octahedral environment and the 2-methyllactato ligand is bidentately chelating. The presence of lattice water molecules mediates the formation of a three-dimensional network.

引用

页码：151 / 154

页数：4

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